Link to "Permalink Settings" is of no use there.

People at support forums already think, it's a per-post setting.

User roles without necessary capability get an error if they click the link which is also shown to them (WP5 beta5). Same for "Change Permalinks" button above title (in case of "plain" permalinks).

Sitewide "one time use" settings for admin roles should never show in a content editing area, especially not to all users.

Users on "one-user-admin" sites might even be encouraged to click the always present "Permalink Settings" link and "play" with different options there, unknowing that they break existing internal links between their pages and posts, and even worse external links saved at and followed by search engines.

TL;DR System settings in content, bad idea, very bad idea.